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76 Operation and Maintenance Manual
Detection Limits
The following table lists the detection limits which can be expected for typical
chromatographic conditions, assuming proper operation of the Detector and
chromatographic systems.
Table 2 Expected Detection Limits for Chromatographic Conditions
Type of Injection Volume Column Detection Limit Per
Compound as Sulfur
Liquid, Split 1:10 1 µL Capillary ≤0.32 mm ID 50 parts per billion
Liquid, Split 1:100 1 µL Capillary ≤0.32 mm ID 0.5 parts per million
Liquid, On-column or splitless 1 µL Capillary ≤0.32 mm ID 5 parts per billion
Liquid, Splitless 10 µL Capillary ≤0.32 mm ID 0.5 parts per billion
Gas, Split 1:10 1 cm
3
Capillary ≤0.32 mm ID 50 parts per billion
Gas, Direct on-column 1 cm
3
0.53 mm ID 5 parts per billion
Gas, Direct on-column 1 cm
3
Packed 5 parts per billion
Gas, Direct on-column 10 cm
3
Packed 0.5 parts per billion